Apparatus for removing oil and debris from water

ABSTRACT

Oil, solid particles such as biological slime and floating debris etc. are removed from water by an apparatus including endless chain means made up of a series of interconnected foraminous chambers holding a regenerable porous filter material such as polyurethane. Preferably the filter material has an outer large pore section and an inner small pore section. A plurality of buckets are attached to the chain means, and as the chain means moves through a closed loop path, these buckets catch debris and dump it into a holding bin. Simultaneously, the filter material absorbs surface and subsurface oil and the like from water traveling through the filter material. The filter material is regenerated by squeezing the filter material to release the oil.

United States Patent Inventors James F. Grutsch Hammond; Russell C. Mallatt, Crown Point, both of 1nd. Appl. No. 20,508 Filed Mar. 18, 1970 Patented Sept. 28, 1971 Assignee Standard Oil Company Chicago, Ill.

APPARATUS FOR REMOVING OIL AND DEBRIS FROM WATER 6 Claims, 6 Drawing Figs.

US. Cl. 210/242, 210/350, 210/391, 210/400, 210/D1G. 21

Int. Cl E021! 15/04 Field of Search... 210/24, 30,

40, 350, 351, 391, 400, 401, 496, 242, DIG. 21

SPIRA L [56] References Cited UNlTED STATES PATENTS 1,789,425 1/1931 Cabrera 210/391 X 3,334,042 8/1967 Teitsma i. 210/40 X Primary Examiner-Samih N. Zaharna Attorneys- Arthur G. Gilkes, William T. McClain and John J.

Connors ABSTRACT: Oil, solid particles such as biological slime and floating debris etc. are removed from water by an apparatus including endless chain means made up of a series of interconnected foraminous chambers holding a regenerable porous filter material such as polyurethane. Preferably the filter material has an outer large pore section and an inner small pore section. A plurality of buckets are attached to the chain means, and as the chain means moves through a closed loop path, these buckets catch debris and dump it into a holding bin. Simultaneously, the filter material absorbs surface and subsurface oil and the like from water traveling through the filter material. The filter material is regenerated by squeezing the filter material to release the oil.

PATENTED sma m1 3,608.72? sum 3 or 4 INVENTORS. James F. Grufscl; C Mal/a" ATTORNEY BACKGROUND In U.S. Pat. No. 3,487,927, Robert L. Yahnke has disclosed oil and water separation equipment which relies on filtration principles. This unique piece of equipment uses, as the filtration medium, a foamed-polyurethane belt trained about a perforateddrum that is rotatably mounted in a waterholding tank into which oil contaminated water is pumped. A differential in pressure is established across the belt and the contaminated water flows through the belt, with the oil being absorbed by the belt. Absorbed oil is subsequently removed from the belt and collected.

BRIEF DESCRIPTION OF THE INVENTION We have now invented an apparatus which can remove oil or the like from water and at the same time recover floating or submerged debris. Debris would normally rupture the delicate pore structure of the filter material used to absorb oil, but our improved apparatus employs screening means external to the filter material which prevents any floating or submerged debris or the like from damaging the filter material. Further, the apparatus solves the problem of skimming oil and debris in very rough water such as on the high seas.

DESCRIPTION OF DRAWINGS FIG. 1 is a schematic side view, partially in cross section, of

our apparatus mounted between the twin hulls of a catamaran.

DESCRIPTION OF PREFERRED EMBODIMENT As depicted in FIG. 1, our apparatus is mounted between the dual hulls of a catamaran. The chief component of our apparatus I0 is endless carrier means 12 including a plurality of foraminous chambers 16 which hold regenerable porous filter material 18. Preferably, filter material 18 is reticulated hydrophobic foam such as polyurethane made of up of an outer large pore section 18a and inner small pore section 18b (FIG. 4). Outer section 18a, typically having 45 or less pores per linear inch, readily entraps viscous oils. Inner section 18b, typically having 60 or more pores per linear inch, readily entraps light fluid oil. The pores of section 18a are substantially larger than the pores of section 18b. Such a multiporosity filter material is less likely to become clogged than a filter material having only a small pore structure. Altemately the different chambers 16 may include foams having different size pore structures.

Each foraminous chamber 16 includes a bucket 14 which serves to collect debris, and each bucket 14 has screen bottom 15, and a pair of end plates 21 having associated therewith side flanges 23. These buckets 14 are connected between two series of endless chain links (FIG. 2) and 22 (FIG. 3) which makes up carrier means 12 and flanges 23 of buckets 14 are bolted to links 20 and 22, as depicted in FIG. 2. Chain links 20 and 22 are trained about sprockets 24 and 26 (FIG. I), andas illustrated in FIGS. 2 and 3, these links include rollers 27, which ride over tips of the sprockets as these sprockets revolve. Sprocket 24, the drive sprocket, is above the water's surface and its drive shaft 28 is connected to drive motor 30. Sprocket 26, the idler sprocket, is below the water's surface and offset relative to drive sprocket 24. The offset arrangement of sprockets 24 and 26 inclines carrier means 12 relative to the horizontal, and the angle of inclination 4 ranges between about 30 and about preferably about 60.

The catamaran also includes debris storing bin 32 between the waters surface and sprocket 24. Screen bottomed buckets l4 catch debris and then dump it into this bin 32. Any liquid picked up by buckets 14 drains through screen bottoms 15 of the buckets and through filter material 18 and is thus purified. To further facilitate debris collection, the catamaran is also equipped with spiral or paddle wheel skimmer 34 in advance of chain means 12. Skimmer 34 directs in a positive manner surface debris and oil towards buckets 14.

FIG. 4 illustrates in detail the structure of foraminous chambers 16. Each of these chambers 16 includes rigid frame 36 secured to bottoms 15 of buckets 14. Frame 36 includes lip 37 for retaining filter material 18 and a movable inner pressure screen 42. Filter material 18 is disposed between screen bottom 15 and movable pressure screen 42, and it is regenerated by compressing it between bottom screen 15 and movable screen 42 to squeeze out absorbed oil. Edge 39 of frame 36 may be spoutlike to aid in directing liberated oil into oil collecting means 58 (FIG. 6) mounted inside the looped path of carrier means 12. Stiffeners 44 are attached to movable pressure screen 42, and as shown in FIG. 6, these stiffeners act in conjunction with pressurizing means 46 to compress filter material 18 between the screens 15 and 42.

The pressurizing means 46, as shown in FIG. 5, includes mounting discs 48 and 50 disposed between the two hexagonal plates 24a and 24b of drive sprocket 24, and elongated members 56 having a C-cross section or grooves 60 mounted on the discs. As carrier means 12 moves through a closed-looped path, stiffeners 56 come into registration with stiffeners 44 and the stiffeners then ride in C-grooves 60 of members 56. This forces pressure screen 42 towards screen bottom 15 and compresses filter material 18 between screens 15 and 42. Oil collecting means 58 then catches oil squeezed from filter material 18.

In operation, drive motor 30 turns drive shaft 28 of sprockets 24 causing carrier means 12 to move through a closed-loop path dipping into the surface water and then being withdrawn. Floating debris is caught in buckets l4 and carried upwardly until it is above storing bin 32. Buckets 14 are then inverted as carrier means 12 moves over sprocket 24 and the debris falls into bin 32. At this point water sprays may be used to clean debris from the screens. Oil and debris contaminated surface waters flow through filtering material 18 due to naturally occuring water currents, currents induced by movement of the catamaran and/or by the paddle wheel or spiral skimmer 34, and the pumping action induced by buckets 14 lifting water. Screen-bottomed buckets 14 retain the debris, and oil is absorbed in the foam's pores. Absorbed oil is then squeezed out of filter material 18 by pressurizing means 46, with liberated oil falling into collecting means 58 and flow flowing or being pumped into a suitable container.

The advantages of our apparatus are manifold. First, foraminous chambers 16 with screen 15 and 42 protect filter material 18 from debris. Oil on the surface of water acts as a collector for solid debris such as floating pieces of wood, leaves, rags, paper, branches, biological slime, etc. Sometimes this debris is so voluminous that it prevents the oil from flowing. At other times, debris is intentionally added, for example, dumping straw on the water to soak up oil. The filter material 18 must be protected from debris, otherwise the debris would make oil recovery difficult if not frequently impossible.

Second, the debris is automatically collected. Most harbors are laden with debris which is both ugly and a major water polluter. Clean up of the debris is expensive because it is normally picked up by hand from small boats. Our multifunctional apparatus is a much more economical way. of collecting debris, and keeping it separate from any fluid oil. Moreover, the removal of debris makes it easier to collect oil.

Third, the particle-to-partiele contact of the oil as it collects and accumulates in the foam causes the oil to coalesce and frequently demulsify to a significant degree.

Fourth, the lifting of oil high above the water establishes a hydraulic head which provides for transfer of the recovered, substantially demulsified oil to a receptacle vessel without using a pump which would remulsify the oil and water. Remulsification would require handling of a larger volume of oilwater emulsion and expensive demulsifying facilities to recover the oil.

Fifth, our apparatus may be extended far below the waters surface to pick up debris in depth, as would be required if a very heavy application of straw was used to soak up oil or if high waves and swells prevailed in the area to be skimmed. Our chain or carrier means 12 can dip into the water as far as necessary to assure continued contact with oil. Thus our apparatus can also be used for skimming in very rough water such as on the high seas.

Sixth, the use of a multiporosity foam following a screenbottomed bucket permits handling, without a changeover in filter material or assembly, both heavy viscous and light fluid oils as well as solid, or semisolid oils solidified by low prevailing temperatures or evaporation of the lighter components.

We Claim:

1. Apparatus useful in removing debris and oil from water, comprising:

revolvable means;

endless carrier means mounted on said revolvable means and carrying means for collecting debris and foraminous chamber means having therein a regenerable porous filter material which selectively absorbs oil, said chamber including movable foraminous means supporting said filter material; means for storing collected debris; drive means for moving said carrier means through a closedloop path so that, as the carrier means is driven, the filter material contacts the oil contaminated water to entrap the oil, and the debris collecting means dips into the water to collect the floating and dispersed debris which is then carried to the debris-storing means and deposited there; means for removing oil from the filter material, said oil removing means being constructed and arranged to move said movable foraminous means to compress the filter material to squeeze oil therefrom; and means for collecting oil squeezed from the filter material, said oil collecting means being inside the closed-loop path of the carrier means, 2. The apparatus of claim 1 wherein said chain means is inclined relative to the horizontal at an angle ranging between about 30 and about 3. The apparatus of claim 1 wherein the filter material is' polyurethane foam.

4. The apparatus of claim 1 wherein the filter material has a large pore outer section and a small pore inner section.

5. The apparatus of claim 1 wherein said carrier means, oil collecting means, and debris-storing means, are mounted on a vessel capable of moving through contaminated water.

6. The apparatus of claim 5 wherein debris-skimming means are mounted on said vessel in advance of the chain means. 

2. The apparatus of claim 1 wherein said chain means is inclined relative to the horizontal at an angle ranging between about 30* And about 90*.
 3. The apparatus of claim 1 wherein the filter material is polyurethane foam.
 4. The apparatus of claim 1 wherein the filter material has a large pore outer section and a small pore inner section.
 5. The apparatus of claim 1 wherein said carrier means, oil collecting means, and debris-storing means, are mounted on a vessel capable of moving through contaminated water.
 6. The apparatus of claim 5 wherein debris-skimming means are mounted on said vessel in advance of the chain means. 